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Glass

Sand and ash fused at high temperature make a material with no natural equivalent.

When
Known to
± 300 years
Era
Bronze Age, Holocene

Glass beads appear in Mesopotamia and Egypt in the third millennium BCE and true glass vessels by around 1500 BCE, formed around a core of clay and dung since blowing has not been invented. It is enormously difficult — high temperature, fussy chemistry, and opaque results unless the ingredients are right — and it stays a luxury. Cuneiform tablets from the second millennium preserve glassmaking recipes, among the oldest technical instructions known.

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